Tuning the breathing behaviour of MIL-53 by cation mixing.

نویسندگان

  • Farid Nouar
  • Thomas Devic
  • Hubert Chevreau
  • Nathalie Guillou
  • Emma Gibson
  • Guillaume Clet
  • Marco Daturi
  • Alexandre Vimont
  • Jean Marc Grenèche
  • Matthew I Breeze
  • Richard I Walton
  • Philip L Llewellyn
  • Christian Serre
چکیده

A mixed cation MIL-53(Cr-Fe) MOF has been obtained by direct synthesis. Multiple experimental techniques have demonstrated the presence of a genuine mixed phase, leading to a breathing behaviour different from either of the single cation analogues.

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عنوان ژورنال:
  • Chemical communications

دوره 48 82  شماره 

صفحات  -

تاریخ انتشار 2012